Instrumental Multi-Element Chemical AnalysisZ.B. Alfassi Springer Science & Business Media, 6 dec 2012 - 506 pagina's The analysis of materials containing several elements used to be a difficult problem for analytical chemists, so a well established sequence of wet chemical qualitative tests were performed to ensure each element was detected. Quantitative tests could then be carried out on the sample, according to the range of elements present. Most analytical chemists were very familiar with these techniques, having been taugth them from a very early stage in their education and careers. The analytical chemist can now call on a range of specialist instrumental techniques which can detect the presence of many elements, often simultaneously, and often quantitatively, providing rapid results on samples which, in the past, could take days. The drawback is that the instruments tend to be expensive, suited to particular sample types or matrices and complex in both setting up and in the interpretation of results. Furthermore the general analytical chemist may have access and familiarity with only one or two methods. Written by an international team of contributors, each experts in their particular fields, this book familiarizes analytical chemists with the range of elemental analysis techniquers, to enable them to specify the most appropriate test for any given sample. In addition, it contains important chapters on sample preparation and quality control, essential elements in obtaining accurate and reliable analytical results. As such, this book will be essential reading for all analytical chemists. The techniques of elemental analysis are important in many other disciplines, so the book will be of particular interest to those commissioning a wide range of analytical measurements, such as chemists, geologists, environmental scientists and biologists. The breadth and depth of coverage will also make the book very useful for advanced students. |
Inhoudsopgave
| 17 | |
References | 53 |
References | 92 |
References | 149 |
Inductively coupled plasma optical emission and mass spectrometry | 151 |
Electroanalytical methods | 201 |
References | 250 |
Analysis of ions using highperformance liquid chromatography | 346 |
Scattering methods | 379 |
References | 435 |
| 490 | |
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Veelvoorkomende woorden en zinsdelen
absorbance acid activation analysis Anal analyte angle anions argon atomic absorption atomic number atoms Auger background backscattering beam calculated calibration carbon cations charge Chem chemical Chromatogr chromatography coefficient compound concentration containing coprecipitation coulometry decay detection limits detector determination electrode eluent emission emitted energy equation example excitation factors Figure flame flux gamma-rays hydrogen ICP-MS incident instrument intensity interferences ion chromatography ion exchange ion-selective electrode ionization irradiation isotope layer linear mass mass spectrometer materials matrix measured membrane metal method mobile phase nebulizer neutron neutron activation analysis nuclear nuclide obtained oxide parameters particles peak photons plasma potential preconcentration radiation radioactive radionuclides range ratio reaction recoil redox relatively sample scattering sensitivity signal SIMS slit solution solvent species spectral spectrometer spectrum standard deviation stopping cross-section surface Table target techniques temperature thermal neutron trace elements tube usually wavelength X-ray x₁
