Journal of the Chemical Society, Volume 69Chemical Society., 1896 |
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Pagina 18
... atom , which acts like the bromine in ammonium bromide ; t in the case of the chlorobromide , the chlorine atom plays an analogous part . Moreover , further experiments on the interaction of ammonia with dibromopropylthiocarbimide ...
... atom , which acts like the bromine in ammonium bromide ; t in the case of the chlorobromide , the chlorine atom plays an analogous part . Moreover , further experiments on the interaction of ammonia with dibromopropylthiocarbimide ...
Pagina 23
... atom , held in closed chain between two other polyvalent atoms . Such a linkage would necessarily entail the withdrawal of the SH hydrogen ( to form hydro- gen bromide ) , and the action would then occur in one of the two following ways ...
... atom , held in closed chain between two other polyvalent atoms . Such a linkage would necessarily entail the withdrawal of the SH hydrogen ( to form hydro- gen bromide ) , and the action would then occur in one of the two following ways ...
Pagina 36
... atom by which its empirical formula differs from that of di- bromocamphor appearing to enter the ring between the carbonyl group and one of the neighbouring carbon atoms . There is every In a preliminary notice of the investigation ...
... atom by which its empirical formula differs from that of di- bromocamphor appearing to enter the ring between the carbonyl group and one of the neighbouring carbon atoms . There is every In a preliminary notice of the investigation ...
Pagina 37
... atoms from the dibromolac- tone , only one is removed by reducing agents . Simultaneously , how- ever , the lactone ring is split , and an unsaturated monobromocar- boxylic acid is produced . This substance , which has the formula ...
... atoms from the dibromolac- tone , only one is removed by reducing agents . Simultaneously , how- ever , the lactone ring is split , and an unsaturated monobromocar- boxylic acid is produced . This substance , which has the formula ...
Pagina 38
... atoms of the halogen , and at once part with hydrogen bromide , yielding a B - bromo - y - lactone . The behaviour of the monobromocarboxylic acid towards sulphuric acid affords further evidence in favour of the view that it is a ẞy ...
... atoms of the halogen , and at once part with hydrogen bromide , yielding a B - bromo - y - lactone . The behaviour of the monobromocarboxylic acid towards sulphuric acid affords further evidence in favour of the view that it is a ẞy ...
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Overige edities - Alles bekijken
Veelvoorkomende woorden en zinsdelen
acetic acid acetyl acetyl chloride action alcohol alkali ammonia ammonium anhydride aniline aqueous atoms axes axis benzene boiling bromine calculated camphene camphoic camphoric acid carbonic oxide cent CH₂ chemical Chemistry chloride CO₂ colouring matter colourless compound containing cooling crystallised crystals cyanate cyanogen decomposed decomposition density derivative determined dilute dissolved distilled dried ethereal salt ethylene ethylic evaporated experiments flame formed formula gave glycerate grams H₂O heated Hofmann hydrochloric acid hydrogen hydrogen bromide hydrogen chloride indices insoluble iodide isomeric liquid luteolin melting point metal method methylic dibenzoylglycerate mixture molecular volume molecular weight molecule nitrogen observed obtained optic axial angle optical ellipsoid oxygen phenyl phosphorus potash potassium precipitate prepared prisms quantity readily refraction refractive indices requires residue rubidium separated silver nitrate sodium sodium carbonate sodium ethoxide soluble solution solvent specific rotation substance sulphate sulphuric acid symmetry temperature tion Trans tube values whilst yield zinc
Populaire passages
Pagina 593 - Now if we take 20 equivalents of carbon, 11 equivalents of hydrogen, 1 equivalent of nitrogen, and 2 equivalents of oxygen, as the composition of quinine, it will be obvious that naphthalidine, differing only by the elements of two equivalents of water, might pass into the former alkaloid simply by an assumption of water. We cannot, of course, expect to induce the water to enter merely by placing it in contact, but a happy experiment may attain this end by the discovery of an appropriate metamorphic...
Pagina 628 - The most superficial glance at the present condition of European states shows, that those which linger in the race cannot hope to escape the partial diminution and perhaps the final annihilation of their resources. It is with nations as with nature, which, according to a happy expression of Goethe, knows no pause in ever-increasing movement, development, and production — a curse still cleaving to standing still.
Pagina 596 - ... than coal-tar naphtha may be used in which the brown substance is soluble and the colouring matter is not soluble. I then free the residue from the naphtha by evaporation, and digest it with methylated spirit, or any other liquid in which the colouring matter is soluble, which dissolves out the new colouring matter. I then separate the methylated spirit from the colouring matter by distillation, at a temperature of 100° C. or 212° F.
Pagina 663 - ... hydrogen, the power of combining with acids has altogether disappeared. In these hydrogen-compounds the gradation of properties is. indeed even more marked than in their trimethylated and triethylated derivatives. On comparing the terminal points of the series, ammonia and antimonietted hydrogen, we cannot fail to be struck by the dissimilarity of properties which at the first glance appears to limit the analogy of the two compounds to a mere parallelism of composition. In the methylated and...
Pagina 596 - At this time neither I nor my friends had seen the inside of a chemical works, and whatever knowledge I had was obtained from books. This, however, was not so serious a drawback as at first it might appear to be, as the kind of apparatus required, and the character of the operations to be performed, were so entirely different from any in use that there was but little to copy from.
Pagina 597 - ... had it not been for this discovery, the coal-tar colour industry could not have been started.
Pagina 595 - Although the results were not so encouraging as could be wished, I was persuaded of the importance of the colouring matter, and the result was that, in October, I sought an interview with my old master Hofmann and told him of the discovery of this dye, showing him patterns dyed with it, at the same time saying that as I was going to undertake its manufacture, I was sorry that I should have to leave the Royal College of Chemistry. At this he appeared annoyed, and spoke in a very discouraging manner,...
Pagina 217 - The flames of cyanogen and acetylene are peculiar in respect that the te'mperature of individual decomposing molecules is not dependent entirely on the temperature generated by the combustion which is a function of the tension of dissociation of the oxidised products, carbonic acid and water. We have no means of defining with any accuracy the temperature which the particles of such a flame may reach. We know, however, that the mean temperature of the flames of carbonic oxide and hydrogen lies between...
Pagina 834 - ... of air comparatively cold. The real temperature of visible flame is perhaps as high as any we are acquainted with. Mr. TENNANT was in the habit of showing an experiment, which demonstrates the intensity of its heat. He used to fuse a small filament of platinum in the flame of a common candle; and it is proved by many facts, that a stream of air may be made to render a metallic body white hot, yet not be itself luminous.
Pagina 526 - BO could, and of such a nature, that what thing soever faullith oute of the rokkes ynto this pitte, or ys caste in, or growith about the rokke and is touched of this water, growith ynto stone ; or...