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although in such an arrangement it must be admitted that there may be an equilibrium, it is evidently unstable, and ill adapted to form the basis of any permanent crystal.
More than three years have now elapsed since a very simple explanation of this difficulty occurred to me. As in the course of that time I had not discovered it to be liable to any crystallographical objection, and as it had appeared 'satisfactory to various mathematical and philosophical friends to whom I proposed it, I had engaged to make this the subject of the Bakerian Lecture of the present year, hoping that some further speculations, connected with the same theory, might lead to more correct notions than are at present entertained of crystallization in general.
At the time when I made this engagement, I flattered myself that the conception might be deserving of attention from its novelty. But I have since found, that it is not altogether so new as I had then supposed it to be; for by the kindness of a friend, I have been referred to Dr. HookE's Micrographia, in which is contained, most clearly, one essential part of the same theory.
However, since the office of a lecturer is properly to diffuse knowledge already acquired, rather than to make known new discoveries in science, and since these hints of Dr. Hooke have been totally overlooked, from having been thrown out at a time when crystallography, as a branch of science, was wholly unknown, and consequently not applied by him to the extent which they may now admit, I have no hesitation in treating the subject as I had before designed. And when I have so done, I shall quote the passage from Dr. Hooke, to shew how ex
HOOKE actly the views which I have taken have, to a certain extent, corresponded with his; and I shall hope that, by the assistance of such authority, they may meet with a more favourable reception.
The theory to which I here allude is this, that, with respect to fluor spar and such other substances as assume the octohedral and tetrahedral forms, all difficulty is removed by supposing the elementary particles to be perfect spheres, which by mutual attraction have assumed that arrangement which brings. them as near to each other as possible.
Tlie relative position of any number of equal balls in the same plane, when gently pressed together, forming equilateral triangles with each other (as represented perspectively in fig. 4.) is familiar to every one; and it is evident that, if balls so placed were cemented together, and the stratum thus formed were afterwards broken, the straight lines in which they would be disposed to separate would form angles of 60° with each other. If a single ball were placed any where at rest upon the
preceding stratum, it is evident that it would be in contact with three of the lower balls (as in fig. 5.), and that the lines joining the centres of four balls so in contact, or the planes touching their surfaces, would include a regular tetrahedron, having all its sides equilateral triangles.
The construction of an octohedron, by means of spheres alore, is as simple as that of the tetrahedron. For if four balls be placed in contact on the same plane in form of a square, then a single ball resting upon them in the centre, being in contact with each pair of balls, will present a triangular face rising from each side of the square, and the whole together will represent the superior apex of an octohedron; so that a
sixth ball similarly placed underneath the square will complete the octohedral group, fig. 6.
There is one observation with regard to these forms that will appear paradoxical, namely, that a structure which in this case was begun upon a square foundation, is really intrinsically the same as that which is begun upon the triangular basis. But if we lay the octohedral group, which consists of six balls, on one of its triangular sides, and consequently with an opposite triangular face uppermost, the two groups, consisting of three balls each, are then situated precisely as they would be found in two adjacent strata of the triangular arrangement. Hence in this position we may readily convert the octohedron into a regular tetrahedron, by addition of four more balls. (fig. 7.) One placed on the top of the three that are uppermost forms the apex; and if the triangular base, on which it rests, be enlarged by addition of three more balls regularly disposed around it, the entire group of ten balls will then be found to represent a regular tetrahedron.
For the purpose of representing the acute rhomboid, two balls must be applied at opposite sides of the smallest octohedral group, as in fig. 9. And if a greater number of balls be placed together, fig. 10 and 11, in the same form, then a complete tetrahedral group may be removed from each extremity, leaving a central octohedron, as may be seen in fig. 11, which corresponds to fig. 3.
The passage of Dr. Hooke, from which I shall quote so much as to connect the sense, is to be found at page 85 of his Micrographia.
“ From this I shall proceed to a second considerable phenomenon,
on, which these diamants (meaning thereby quartz
crystals) exhibit, and that is the regularity of their figure
-This I take to proceed from the most simple principle “ that any kind of form can come from, next the globular; “ for I think I could make probable, that all these regular
figures arise only from three or four several positions or
postures of globular particles, and those the most plain and “ obvious, and necessary conjunctions of such figured particles " that are possible And this I have ad oculum demonstrated " “ with a company of bullets, so that there was not any regu“ lar figure which I have hitherto met withal of any of those “ bodies that I have above named, that I could not with the
composition of bullets or globules imitate almost by shaking 's them together.
Thus, for instance, we find that globular bullets will of themselves, if put on an inclining plain so that they may “ run together, naturally run into a triangular order compos
ing all the variety of figures that can be imagined out of “ equilateral triangles, and such you will find upon trial all the “ surfaces of alum to be composed of
“—nor does it hold only in superficies, but in solidity also; “ for it's obvious that a fourth globule laid upon the third in “ this texture composes a regular tetrahedron, which is a very “ usual figure of the crystals of alum. And there is no one
figure into which alum is observed to be crystallized, but
may by this texture of globules be imitated, and by no “ other.”
It does not appear in what manner this most ingenious philosopher thought of applying this doctrine to the formation of quartz crystal, of vitriol, of salt-petre, &c. which he names. This remains among the many hints which the peculiar jealousy
of his temper left unintelligible at the time they were written, and which, notwithstanding his indefatigable industry, were subsequently lost to the public, for want of being fully developed.
We have seen, that by due application of spheres to each other, all the most simple forms of one species of crystal will be produced, and it is needless to pursue any other modifications of the same form, which must result from a series of decrements produced according to known laws.
Since then the simplest arrangement of the most siinple solid that can be imagined, affords so complete a solution of one of the most difficult questions in crystallography, we are naturally led to inquire what forms would probably occur from the union of other solids most nearly allied to the sphere. And it will appear that by the supposition of elementary particles that are spheroidical, we may frame conjectures as to the origin of other angular solids well known to crystallographers.
The obtuse Rhomboid.
If we suppose the axis of our elementary spheroid to be its shortest dimension, a class of solids will be formed which are numerous in crystallography. It has been remarked above, that by the natural grouping of spherical particles, fig. 10, one resulting solid is an acute rhomboid, similar to that of fig. 2, having certain determinate angles, and its greatest dimension in the direction of its axis. Now, if other particles having the same relative arrangement be supposed to have the form of oblate spheroids, the resulting solid, fig. 12, will still be a regular rhomboid; but the measures of its angles will be different from those of the former, and will be more